Literature DB >> 20929225

Hydrogen-atom abstraction from Ni(I) phosphido and amido complexes gives phosphinidene and imide ligands.

Vlad M Iluc1, Gregory L Hillhouse.   

Abstract

Hydrogen-atom abstraction from M-E(H) to generate M═E-containing complexes (E = PR, NR) is not well studied because only a few complexes are known to undergo such reactions. Hydrogen-atom abstraction from nickel(I) phosphide and amide complexes led to the corresponding phosphinidene and imide compounds. These reactions are unparalleled in the organometallic chemistry of nickel and feature an unusual example of a transition-metal phosphinidene synthesized by hydrogen-atom abstraction.

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Year:  2010        PMID： 20929225     DOI： 10.1021/ja107115q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Arene C-H amination at nickel in terphenyl-diphosphine complexes with labile metal-arene interactions.

Authors:  David E Herbert; Nadia C Lara; Theodor Agapie
Journal:  Chemistry       Date:  2013-10-14       Impact factor: 5.236

2.  Synthesis and characterization of three-coordinate Ni(III)-imide complexes.

Authors:  Vlad M Iluc; Alexander J M Miller; John S Anderson; Marisa J Monreal; Mark P Mehn; Gregory L Hillhouse
Journal:  J Am Chem Soc       Date:  2011-07-28       Impact factor: 15.419

3.  Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2.

Authors:  Konstantin V Bukhryakov; Richard R Schrock; Amir H Hoveyda; Peter Müller; Jonathan Becker
Journal:  Org Lett       Date:  2017-05-01       Impact factor: 6.005

4.  Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide.

Authors:  Nathaniel J Hartmann; Guang Wu; Trevor W Hayton
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-12       Impact factor: 15.336

5.  Homolytic N-H activation of ammonia: hydrogen transfer of parent iridium ammine, amide, imide, and nitride species.

Authors:  Markus G Scheibel; Josh Abbenseth; Markus Kinauer; Frank W Heinemann; Christian Würtele; Bas de Bruin; Sven Schneider
Journal:  Inorg Chem       Date:  2015-07-20       Impact factor: 5.165

6.  Carbon-hydrogen bond activation, C-N bond coupling, and cycloaddition reactivity of a three-coordinate nickel complex featuring a terminal imido ligand.

Authors:  Daniel J Mindiola; Rory Waterman; Vlad M Iluc; Thomas R Cundari; Gregory L Hillhouse
Journal:  Inorg Chem       Date:  2014-12-01       Impact factor: 5.165

7.  Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer.

Authors:  Josh Abbenseth; Daniel Delony; Marc C Neben; Christian Würtele; Bas de Bruin; Sven Schneider
Journal:  Angew Chem Int Ed Engl       Date:  2019-04-01       Impact factor: 15.336

8.  C-H Bond Activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex.

Authors:  Alexander Reckziegel; Clemens Pietzonka; Florian Kraus; C Gunnar Werncke
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-27       Impact factor: 15.336

9.  Synthesis, characterization and C-H amination reactivity of nickel iminyl complexes.

Authors:  Yuyang Dong; James T Lukens; Ryan M Clarke; Shao-Liang Zheng; Kyle M Lancaster; Theodore A Betley
Journal:  Chem Sci       Date:  2019-12-11       Impact factor: 9.969
  9 in total

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