Literature DB >> 20919715

B(C6F5)3-promoted tandem silylation and intramolecular hydrosilylation: diastereoselective synthesis of oxasilinanes and oxasilepanes.

Roman Shchepin1, Chunping Xu, Patrick Dussault.   

Abstract

B(C(6)F(5))(3) promotes regio- and stereoselective cyclizations of unsaturated alkoxysilanes to generate oxasilinanes and oxasilepanes. The same products are available directly from alkenols via tandem silylation and hydrosilylation.

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Year:  2010        PMID： 20919715      PMCID： PMC2967452          DOI： 10.1021/ol1018757

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  10 in total

1.  Stereocontrol in intramolecular hydrosilylation of allyl and homoallyl alcohols: a new approach to the stereoselective synthesis of 1,3-diol skeletons.

Authors:  K Tamao; T Nakajima; R Sumiya; H Arai; N Higuchi; Y Ito
Journal:  J Am Chem Soc       Date:  1986-09-01       Impact factor: 15.419

2.  Fully reagent-controlled asymmetric synthesis of (-)-spongidepsin via the Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction).

Authors:  Gangguo Zhu; Ei-ichi Negishi
Journal:  Org Lett       Date:  2007-06-21       Impact factor: 6.005

3.  Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions.

Authors:  Gerhard Erker
Journal:  Dalton Trans       Date:  2005-04-29       Impact factor: 4.390

4.  A direct reduction of aliphatic aldehyde, acyl chloride, ester, and carboxylic functions into a methyl group.

Authors:  V Gevorgyan; M Rubin; J X Liu; Y Yamamoto
Journal:  J Org Chem       Date:  2001-03-09       Impact factor: 4.354

5.  A novel B(C(6)F(5))(3)-catalyzed reduction of alcohols and cleavage of aryl and alkyl ethers with hydrosilanes

Authors: 
Journal:  J Org Chem       Date:  2000-09-22       Impact factor: 4.354

Review 6.  Synthetic and mechanistic studies of the cycloisomerization and cyclization/hydrosilylation of functionalized dienes catalyzed by cationic palladium(II) complexes.

Authors:  Ross A Widenhoefer
Journal:  Acc Chem Res       Date:  2002-10       Impact factor: 22.384

7.  Studies on the mechanism of B(C(6)F(5))(3)-catalyzed hydrosilation of carbonyl functions

Authors: 
Journal:  J Org Chem       Date:  2000-05-19       Impact factor: 4.354

8.  B(C(6)F(5))(3)-Catalyzed Silation of Alcohols: A Mild, General Method for Synthesis of Silyl Ethers.

Authors:  James M. Blackwell; Katherine L. Foster; Victoria H. Beck; Warren E. Piers
Journal:  J Org Chem       Date:  1999-06-25       Impact factor: 4.354

9.  Highly efficient B(C(6)F(5))(3)-catalyzed hydrosilylation of olefins.

Authors:  Michael Rubin; Todd Schwier; Vladimir Gevorgyan
Journal:  J Org Chem       Date:  2002-03-22       Impact factor: 4.354

10.  Stereoselective synthesis of syn,syn- and syn,anti-1,3,5-triols via intramolecular hydrosilylation of substituted pent-3-en-1,5-diols.

Authors:  Fangzheng Li; William R Roush
Journal:  Org Lett       Date:  2009-07-02       Impact factor: 6.005
  10 in total
  1 in total

1.  Stereoselective isoxazolidine synthesis via copper-catalyzed alkene aminooxygenation.

Authors:  Shuklendu D Karyakarte; Thomas P Smith; Sherry R Chemler
Journal:  J Org Chem       Date:  2012-08-15       Impact factor: 4.354
  1 in total

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