Single ion and dimerization studies of the Al(III) ion in aqueous solution.

Aqueous trivalent aluminum (Al) ions and their oligomers play important roles in diverse areas, such as environmental sciences and medicine. The geometries of octahedral Al(H(2)O)(6)(3+) and tetrahedral Al(OH)(4)(-) species have been studied extensively. However, structures of intermediate hydrolysis products of the Al(III) ion, such as the penta-coordinated Al(OH)(2+) species, which exists at pH values ranging from 3.0 to 4.3, and their mode of formation have been poorly understood. Here, we present that a trigonal bipyramidal Al(OH)(H(2)O)(4)(2+) structure is formed in aqueous solution and how this monomeric species dimerizes to a dinuclear [(H(2)O)(4)Al(OH)(2)Al(H(2)O)(4)](4+) complex in aqueous solution. The Gibbs free energy change calculations indicate that the formation of the dinuclear complex is preferred over the existence of two single trigonal bipyramidal Al(OH)(H(2)O)(4)(2+) species in aqueous solution. This study captures the solution dynamics and proton transfer in the oligomerization reactions of penta-coordinated Al(OH)(2+) species in aqueous solution.