Literature DB >> 20877842

Synthesis, characterization and property of a mixed-valent Ag(I)/Ag(II) coordination polymer.

Di Sun1, Cheng-Feng Yang, Hao-Ran Xu, Hai-Xia Zhao, Zhan-Hua Wei, Na Zhang, La-Jia Yu, Rong-Bin Huang, Lan-Sun Zheng.   

Abstract

A novel mixed-valent Ag(I)/Ag(II) coordination polymer {[Ag(I)(2)Ag(II)(0.5)(SO(4))(HSO(4))(pyz)(2.5)]·H(2)O}(n) (1, pyz = pyrazine) was synthesized and characterized. The results show it presents semiconducting and photoluminescent properties.

Entities:  

Year:  2010        PMID: 20877842     DOI: 10.1039/c0cc02112a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures.

Authors:  Donghoon Seoung; Yongmoon Lee; Hyunchae Cynn; Changyong Park; Kwang-Yong Choi; Douglas A Blom; William J Evans; Chi-Chang Kao; Thomas Vogt; Yongjae Lee
Journal:  Nat Chem       Date:  2014-07-20       Impact factor: 24.427

2.  Crystal structure of μ-cyanido-1:2κ(2) N:C-dicyanido-1κC,2κC-bis-(quinolin-8-amine-1κ(2) N,N')-2-silver(I)-1-silver(II): rare occurrence of a mixed-valence Ag(I,II) compound.

Authors:  Zouaoui Setifi; Sylvain Bernès; Olivier Pérez; Fatima Setifi; Djamil-Azzeddine Rouag
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-05-23
  2 in total

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