Literature DB >> 20866053

Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds.

Tomonari Ureshino1, Takuya Yoshida, Yoichiro Kuninobu, Kazuhiko Takai.   

Abstract

The rhodium-catalyzed synthesis of silafluorenes from biphenylhydrosilanes is described. This highly efficient reaction proceeds via both Si-H and C-H bond activation, producing only H(2) as a side product. Using this method, a ladder-type bis-silicon-bridged p-terphenyl could also be synthesized.

Entities:  

Year:  2010        PMID： 20866053     DOI： 10.1021/ja107698p

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  15 in total

1.  General and practical one-pot synthesis of dihydrobenzosiloles from styrenes.

Authors:  Alexey Kuznetsov; Vladimir Gevorgyan
Journal:  Org Lett       Date:  2012-01-24       Impact factor: 6.005

2.  Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols.

Authors:  Caleb Karmel; Bijie Li; John F Hartwig
Journal:  J Am Chem Soc       Date:  2018-01-22       Impact factor: 15.419

3.  Rhodium-catalyzed enantioselective silylation of arene C-H bonds: desymmetrization of diarylmethanols.

Authors:  Taegyo Lee; Tyler W Wilson; Robert Berg; Per Ryberg; John F Hartwig
Journal:  J Am Chem Soc       Date:  2015-05-20       Impact factor: 15.419

4.  Fused heteroaromatic dihydrosiloles: synthesis and double-fold modification.

Authors:  Alexey Kuznetsov; Yoshiharu Onishi; Yoshihiro Inamoto; Vladimir Gevorgyan
Journal:  Org Lett       Date:  2013-04-29       Impact factor: 6.005

Review 5.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

6.  The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes.

Authors:  Chunhui Huang; Natalia Chernyak; Alexander S Dudnik; Vladimir Gevorgyan
Journal:  Adv Synth Catal       Date:  2011-05-01       Impact factor: 5.837

7.  Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of Dioxasilines.

Authors:  Yuanda Hua; Parham Asgari; Thirupataiah Avullala; Junha Jeon
Journal:  J Am Chem Soc       Date:  2016-06-16       Impact factor: 15.419

Review 8.  Development of Chiral Ligands for the Transition-Metal-Catalyzed Enantioselective Silylation and Borylation of C-H Bonds.

Authors:  Bo Su; John F Hartwig
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-21       Impact factor: 16.823

9.  One-shot K-region-selective annulative π-extension for nanographene synthesis and functionalization.

Authors:  Kyohei Ozaki; Katsuaki Kawasumi; Mari Shibata; Hideto Ito; Kenichiro Itami
Journal:  Nat Commun       Date:  2015-02-16       Impact factor: 14.919

10.  Intramolecular Chain Hydrosilylation of Alkynylphenylsilanes Using a Silyl Cation as a Chain Carrier.

Authors:  Hidekazu Arii; Kenichi Nakabayashi; Kunio Mochida; Takayuki Kawashima
Journal:  Molecules       Date:  2016-08-01       Impact factor: 4.411
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.