Literature DB >> 20859591

Various polystyrene topologies built from tailored cyclic polystyrene via CuAAC reactions.

Daria E Lonsdale1, Michael J Monteiro.   

Abstract

Rapid CuAAC cross-coupling reactions catalyzed by CuBr/PMDETA in toluene afforded complex architectures from functional polymeric cyclic blocks. Various topologies (from paddle-like to 3-arm stars) rapidly formed with high conversion at 25 °C. Remarkably, this approach overcame significant steric hindrance linking polymeric cyclic structures with high coupling efficiency.

Entities:  

Year:  2010        PMID: 20859591     DOI: 10.1039/c0cc02904a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Polymer folding: ABC of molecular origami.

Authors:  Sébastien Perrier
Journal:  Nat Chem       Date:  2011-03       Impact factor: 24.427

2.  Rapid Synthesis of Block and Cyclic Copolymers via Click Chemistry in the Presence of Copper Nanoparticles.

Authors:  Eric D Pressly; Roey J Amir; Craig J Hawker
Journal:  J Polym Sci A Polym Chem       Date:  2011-02       Impact factor: 2.702

3.  Controlled folding of synthetic polymer chains through the formation of positionable covalent bridges.

Authors:  Bernhard V K J Schmidt; Nina Fechler; Jana Falkenhagen; Jean-François Lutz
Journal:  Nat Chem       Date:  2011-01-23       Impact factor: 24.427

  3 in total

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