| Literature DB >> 20852811 |
Aaron D Finke1, Jeffrey S Moore.
Abstract
The substantial kinetic barrier to molybdenum nitride-alkyne metathesis is facilitated by precomplexation of the borane Lewis acid B(C(6)F(5))(3), providing convenient access to metathesis-active molybdenum alkylidynes. Spectroscopic and X-ray structural analysis suggest Mo≡N bond weakening upon borane complexation.Entities:
Year: 2010 PMID： 20852811 DOI： 10.1039/c0cc03113e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222