Literature DB >> 20849109

Metal insertion in a microporous metal-organic framework lined with 2,2'-bipyridine.

Eric D Bloch1, David Britt, Chain Lee, Christian J Doonan, Fernando J Uribe-Romo, Hiroyasu Furukawa, Jeffrey R Long, Omar M Yaghi.   

Abstract

Reaction of AlCl(3)·6H(2)O with 2,2'-bipyridine-5,5'-dicarboxylic acid (H(2)bpydc) affords Al(OH)(bpydc) (1, MOF-253), the first metal-organic framework with open 2,2'-bipyridine (bpy) coordination sites. The material displays a BET surface area of 2160 m(2)/g and readily complexes metals to afford, for example, 1·xPdCl(2) (x = 0.08, 0.83) and 1·0.97Cu(BF(4))(2). EXAFS spectroscopy performed on 1·0.83PdCl(2) reveals the expected square planar coordination geometry, matching the structure of the model complex (bpy)PdCl(2). Significantly, the selectivity factor for binding CO(2) over N(2) under typical flue gas conditions is observed to increase from 2.8 in 1 to 12 in 1·0.97Cu(BF(4))(2).

Entities:  

Year:  2010        PMID： 20849109     DOI： 10.1021/ja106935d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  19 in total

1.  Self-Assembly of Coordinative Supramolecular Polygons with Open Binding Sites.

Authors:  Yao-Rong Zheng; Ming Wang; Shiho Kobayashi; Peter J Stang
Journal:  Tetrahedron Lett       Date:  2011-04-27       Impact factor: 2.415

2.  X-ray crystallographic insights into post-synthetic metalation products in a metal-organic framework.

Authors:  Michael T Huxley; Campbell J Coghlan; Witold M Bloch; Alexandre Burgun; Christian J Doonan; Christopher J Sumby
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-01-13       Impact factor: 4.226

3.  Postsynthetic Metalation of a Robust Hydrogen-Bonded Organic Framework for Heterogeneous Catalysis.

Authors:  Bin Han; Hailong Wang; Chiming Wang; Hui Wu; Wei Zhou; Banglin Chen; Jianzhuang Jiang
Journal:  J Am Chem Soc       Date:  2019-05-23       Impact factor: 15.419

4.  Single-crystal-to-single-crystal intercalation of a low-bandgap superatomic crystal.

Authors:  Evan S O'Brien; M Tuan Trinh; Rose L Kann; Jia Chen; Giselle A Elbaz; Amrita Masurkar; Timothy L Atallah; Maria V Paley; Nilam Patel; Daniel W Paley; Ioannis Kymissis; Andrew C Crowther; Andrew J Millis; David R Reichman; X-Y Zhu; Xavier Roy
Journal:  Nat Chem       Date:  2017-08-14       Impact factor: 24.427

Review 5.  Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

Authors:  Timothy R Cook; Yao-Rong Zheng; Peter J Stang
Journal:  Chem Rev       Date:  2012-11-02       Impact factor: 60.622

6.  Capturing snapshots of post-synthetic metallation chemistry in metal-organic frameworks.

Authors:  Witold M Bloch; Alexandre Burgun; Campbell J Coghlan; Richmond Lee; Michelle L Coote; Christian J Doonan; Christopher J Sumby
Journal:  Nat Chem       Date:  2014-09-07       Impact factor: 24.427

7.  (5,5'-Dimethyl-2,2'-bipyridine)-iodido-trimethyl-platinum(IV).

Authors:  Fredrik Lundvall; David Stephen Wragg; Mats Tilset
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-04-22

8.  Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs).

Authors:  Minghui Zhang; Liangliang Zhang; Zhenyu Xiao; Qinhui Zhang; Rongming Wang; Fangna Dai; Daofeng Sun
Journal:  Sci Rep       Date:  2016-02-09       Impact factor: 4.379

9.  Polyethyleneimine incorporated metal-organic frameworks adsorbent for highly selective CO2 capture.

Authors:  Yichao Lin; Qiuju Yan; Chunlong Kong; Liang Chen
Journal:  Sci Rep       Date:  2013       Impact factor: 4.379

10.  High methane storage capacity in aluminum metal-organic frameworks.

Authors:  Felipe Gándara; Hiroyasu Furukawa; Seungkyu Lee; Omar M Yaghi
Journal:  J Am Chem Soc       Date:  2014-03-24       Impact factor: 15.419
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