Literature DB >> 20848038

Metal-free deprotonative functionalization of heteroaromatics using organic superbase catalyst.

Yutaro Hirono1, Koji Kobayashi, Misato Yonemoto, Yoshinori Kondo.   

Abstract

Metal-free deprotonative functionalization of heteroaromatic compounds was achieved using an organic superbase catalyst; an organosilicon additive such as trimethylsilylpropyne was employed for activating the catalytic cycle of 1,2-addition to carbonyl compounds.

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Year:  2010        PMID: 20848038     DOI: 10.1039/c0cc03106b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Intercepting the Breslow intermediate via Claisen rearrangement: synthesis of complex tertiary alcohols without organometallic reagents.

Authors:  Sefat Alwarsh; Kolawole Ayinuola; Silvana S Dormi; Matthias C McIntosh
Journal:  Org Lett       Date:  2012-12-05       Impact factor: 6.005

2.  Sequencing conjugated polymers by eye.

Authors:  Daniel A Warr; Luís M A Perdigão; Harry Pinfold; Jonathan Blohm; David Stringer; Anastasia Leventis; Hugo Bronstein; Alessandro Troisi; Giovanni Costantini
Journal:  Sci Adv       Date:  2018-06-15       Impact factor: 14.136

  2 in total

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