Literature DB >> 20845972

Reversible O-O bond cleavage and formation between Mn(IV)-peroxo and Mn(V)-oxo corroles.

Sun Hee Kim1, Hyejin Park, Mi Sook Seo, Minoru Kubo, Takashi Ogura, Jan Klajn, Daniel T Gryko, Joan Selverstone Valentine, Wonwoo Nam.   

Abstract

Mn(IV)-peroxo and Mn(V)-oxo corroles were synthesized and characterized with various spectroscopic techniques. The intermediates were directly used in O-O bond cleavage and formation reactions. Upon addition of proton to the Mn(IV)-peroxo corrole, the formation of the Mn(V)-oxo corrole was observed. Interestingly, addition of base to the Mn(V)-oxo corrole afforded the formation of the Mn(IV)-peroxo corrole. Thus, we were able to report the first example of reversible O-O bond cleavage and formation reactions using in situ generated Mn(IV)-peroxo and Mn(V)-oxo corroles.

Entities:  

Mesh：

Substances：

Year:  2010        PMID： 20845972     DOI： 10.1021/ja1066465

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  14 in total

1.  Preparation and Properties of an MnIV-Hydroxide Complex: Proton and Electron Transfer at a Mononuclear Manganese Site and its Relationship to the Oxygen Evolving Complex within Photosystem II.

Authors:  Taketo Taguchi; Kari L Stone; Rupal Gupta; Benedikt Kaiser-Lassalle; Junko Yano; Michael P Hendrich; A S Borovik
Journal:  Chem Sci       Date:  2014-08-01       Impact factor: 9.825

Review 2.  Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins.

Authors:  Xiongyi Huang; John T Groves
Journal:  Chem Rev       Date:  2017-12-29       Impact factor: 60.622

3.  Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate Framework.

Authors:  Roy E Schreiber; Hagai Cohen; Gregory Leitus; Sharon G Wolf; Ang Zhou; Lawrence Que; Ronny Neumann
Journal:  J Am Chem Soc       Date:  2015-06-29       Impact factor: 15.419

4.  Preparation and properties of a monomeric high-spin Mn(V)-oxo complex.

Authors:  Taketo Taguchi; Rupal Gupta; Benedikt Lassalle-Kaiser; David W Boyce; Vittal K Yachandra; William B Tolman; Junko Yano; Michael P Hendrich; A S Borovik
Journal:  J Am Chem Soc       Date:  2012-01-20       Impact factor: 15.419

5.  A Terminal FeIII-Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity.

Authors:  Christopher J Reed; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2019-06-10       Impact factor: 15.419

6.  Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex.

Authors:  Seungwoo Hong; Kyle D Sutherlin; Jiyoung Park; Eunji Kwon; Maxime A Siegler; Edward I Solomon; Wonwoo Nam
Journal:  Nat Commun       Date:  2014-12-16       Impact factor: 14.919

7.  The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities.

Authors:  Evan E Joslin; Jan Paulo T Zaragoza; Regina A Baglia; Maxime A Siegler; David P Goldberg
Journal:  Inorg Chem       Date:  2016-08-16       Impact factor: 5.165

8.  Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification.

Authors:  Julie A Kovacs
Journal:  Acc Chem Res       Date:  2015-09-03       Impact factor: 22.384

9.  Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes.

Authors:  Regina A Baglia; Jan Paulo T Zaragoza; David P Goldberg
Journal:  Chem Rev       Date:  2017-10-09       Impact factor: 60.622

10.  Dioxygen Activation and O-O Bond Formation Reactions by Manganese Corroles.

Authors:  Mian Guo; Yong-Min Lee; Ranjana Gupta; Mi Sook Seo; Takehiro Ohta; Hua-Hua Wang; Hai-Yang Liu; Sunder N Dhuri; Ritimukta Sarangi; Shunichi Fukuzumi; Wonwoo Nam
Journal:  J Am Chem Soc       Date:  2017-10-31       Impact factor: 15.419
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.