Literature DB >> 20843085

Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β-diarylacrylates.

Yuk-Tai Tsoi1, Zhongyuan Zhou, Albert S C Chan, Wing-Yiu Yu.   

Abstract

A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with α-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-α,β-diarylacrylates were obtained in good yields and >20:1 E-to-Z selectivity.

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Year:  2010        PMID： 20843085     DOI： 10.1021/ol101796t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  P(NMe2)3-Mediated Umpolung Alkylation and Nonylidic Olefination of α-Keto Esters.

Authors:  Sunewang Rixin Wang; Alexander T Radosevich
Journal:  Org Lett       Date:  2015-07-15       Impact factor: 6.005

2.  Arylation of rhodium(II) azavinyl carbenes with boronic acids.

Authors:  Nicklas Selander; Brady T Worrell; Stepan Chuprakov; Subash Velaparthi; Valery V Fokin
Journal:  J Am Chem Soc       Date:  2012-08-28       Impact factor: 15.419

3.  Direct Synthesis of 5-Aryl Barbituric Acids by Rhodium(II)-Catalyzed Reactions of Arenes with Diazo Compounds.

Authors:  Daniel Best; David J Burns; Hon Wai Lam
Journal:  Angew Chem Int Ed Engl       Date:  2015-05-08       Impact factor: 15.336

Review 4.  Application of the Suzuki-Miyaura reaction in the synthesis of flavonoids.

Authors:  Mamoalosi A Selepe; Fanie R Van Heerden
Journal:  Molecules       Date:  2013-04-22       Impact factor: 4.411

Review 5.  Preparation and Synthetic Applications of Five-to-Seven-Membered Cyclic α-Diazo Monocarbonyl Compounds.

Authors:  Daniil Zhukovsky; Dmitry Dar'in; Olga Bakulina; Mikhail Krasavin
Journal:  Molecules       Date:  2022-03-21       Impact factor: 4.411
  5 in total

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