Literature DB >> 20843081

An N-heterocyclic carbene-disilyne complex and its reactivity toward ZnCl2.

Torahiko Yamaguchi1, Akira Sekiguchi, Matthias Driess.   

Abstract

The reaction of disilyne 1 with 1,3,4,5-tetramethylimidazol-2-ylidene (an N-heterocyclic carbene, NHC) produced the disilyne-NHC complex 2, RLSi═SiR: (R = Si(i)Pr[CH(SiMe(3))(2)](2), L = NHC), with a trans geometry of the Si═Si moiety and lone-pair electrons residing on one of the double-bonded Si atoms. Upon complexation of 2 with ZnCl(2), the disilyne-NHC-ZnCl(2) complex 3 was produced, in which the Si═Si bond adopted the cis geometry.

Entities:  

Year:  2010        PMID： 20843081     DOI： 10.1021/ja107160g

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene.

Authors:  Michael J Cowley; Volker Huch; Henry S Rzepa; David Scheschkewitz
Journal:  Nat Chem       Date:  2013-09-15       Impact factor: 24.427

2.  Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N3)].

Authors:  Anindya K Swarnakar; Christian Hering-Junghans; Michael J Ferguson; Robert McDonald; Eric Rivard
Journal:  Chem Sci       Date:  2016-12-19       Impact factor: 9.825

3.  NHC-Coordinated Diphosphene-Stabilized Gold(I) Hydride and Its Reversible Conversion to Gold(I) Formate with CO2.

Authors:  Debabrata Dhara; Shubhajit Das; Swapan K Pati; David Scheschkewitz; Vadapalli Chandrasekhar; Anukul Jana
Journal:  Angew Chem Int Ed Engl       Date:  2019-09-12       Impact factor: 15.336
  3 in total

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