Literature DB >> 20839778

Guest escape and uptake in nonporous crystals of a gold(I) macrocycle.

Andrea Deák1, Tünde Tunyogi, Zoltán Károly, Szilvia Klébert, Gábor Pálinkás.   

Abstract

The nonporous gold(I) diphosphine complex [Au(2)(cis-dppe)(2)](NO(3))(2) [1, cis-dppe = cis-1,2-bis(diphenylphosphino)ethylene] is robust enough to trap guests, but at the same time, it is flexible enough to allow guest release without destruction of its crystal lattice. This nonporous gold(I) compound 1 is also efficient at capturing and releasing carbon dioxide in a controlled manner.

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Year:  2010        PMID: 20839778     DOI: 10.1021/ja105458e

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  2 in total

1.  Photoinduced single-crystal-to-single-crystal phase transition and photosalient effect of a gold(i) isocyanide complex with shortening of intermolecular aurophilic bonds.

Authors:  Tomohiro Seki; Kenta Sakurada; Mai Muromoto; Hajime Ito
Journal:  Chem Sci       Date:  2014-12-15       Impact factor: 9.825

2.  Gold(I/III)-Phosphine Complexes as Potent Antiproliferative Agents.

Authors:  Jong Hyun Kim; Evan Reeder; Sean Parkin; Samuel G Awuah
Journal:  Sci Rep       Date:  2019-08-26       Impact factor: 4.379

  2 in total

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