Literature DB >> 20838692

Selective α-defluorination of polyfluorinated esters and amides using SmI2/Et3N/H2O.

Jenny Wettergren1, Tobias Ankner, Göran Hilmersson.   

Abstract

SmI(2)/H(2)O promotes selective α-monodefluorinations, while addition of an amine results in complete α-defluorination reactions.

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Year:  2010        PMID： 20838692     DOI： 10.1039/c0cc02009e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy.

Authors:  Linxuan Li; Xinyu Zhang; Yongquan Ning; Xiaolong Zhang; Binbin Liu; Zhansong Zhang; Paramasivam Sivaguru; Giuseppe Zanoni; Shuang Li; Edward A Anderson; Xihe Bi
Journal:  Nat Commun       Date:  2022-07-25       Impact factor: 17.694

2.  Photocatalytic defluoroalkylation and hydrodefluorination of trifluoromethyls using o-phosphinophenolate.

Authors:  Can Liu; Ni Shen; Rui Shang
Journal:  Nat Commun       Date:  2022-01-17       Impact factor: 14.919

3.  Development of an additive-controlled, SmI2-mediated stereoselective sequence: Telescoped spirocyclisation, lactone reduction and Peterson elimination.

Authors:  Brice Sautier; Karl D Collins; David J Procter
Journal:  Beilstein J Org Chem       Date:  2013-07-18       Impact factor: 2.883
  3 in total

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