Literature DB >> 20836094

Late-transition-metal complexes as tunable Lewis bases.

Jürgen Bauer1, Holger Braunschweig, Peter Brenner, Katharina Kraft, Krzysztof Radacki, Katrin Schwab.   

Abstract

Syntheses of the first heteroleptic N-heterocyclic carbene (NHC)-phosphane platinum(0) complexes and formation of the corresponding Lewis acid-base adducts with aluminum chloride is reported. The influence of N-heterocyclic carbenes on tuning the Lewis basic properties of the metal complexes was judged from spectroscopic, structural, and computational data. Conclusive experimental evidence for the enhanced Lewis basicity of NHC-containing complexes was provided by a transfer reaction.

Entities:  

Year:  2010        PMID： 20836094     DOI： 10.1002/chem.201001228

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  4 in total

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Journal:  Coord Chem Rev       Date:  2021-02-07       Impact factor: 22.315

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Authors:  Holger Braunschweig; Mehmet Ali Celik; Rian D Dewhurst; Magdalena Heid; Florian Hupp; Sakya S Sen
Journal:  Chem Sci       Date:  2014-10-15       Impact factor: 9.825

4.  Bite-angle bending as a key for understanding group-10 metal reactivity of d10-[M(NHC)2] complexes with sterically modest NHC ligands.

Authors:  Florian Hering; Jörn Nitsch; Ursula Paul; Andreas Steffen; F Matthias Bickelhaupt; Udo Radius
Journal:  Chem Sci       Date:  2014-12-03       Impact factor: 9.825
  4 in total

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