Literature DB >> 20835470

Intramolecular light induced activation of a Salen-Mn(III) complex by a ruthenium photosensitizer.

Christian Herrero1, Joseph L Hughes, Annamaria Quaranta, Nicholas Cox, A William Rutherford, Winfried Leibl, Ally Aukauloo.   

Abstract

We have designed a molecular system consisting of a heteroleptic [Ru(bpy)(2)L](2+) chromophore covalently linked to a Mn(III)-Salen unit. We demonstrate the light induced oxidation of the Mn(III) center in this putative photo-catalyst assembly to a Mn(IV) high spin intermediate. Both oxidation states have been characterized by transient absorption and EPR techniques.

Entities:  

Mesh：

Substances：

Year:  2010        PMID： 20835470     DOI： 10.1039/c0cc01710h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Light-driven water oxidation for solar fuels.

Authors:  Karin J Young; Lauren A Martini; Rebecca L Milot; Robert C Snoeberger; Victor S Batista; Charles A Schmuttenmaer; Robert H Crabtree; Gary W Brudvig
Journal:  Coord Chem Rev       Date:  2012-11-01       Impact factor: 22.315

2.  Electrochemical and spectroscopic effects of mixed substituents in bis(phenolate)-copper(II) galactose oxidase model complexes.

Authors:  Russell C Pratt; Christopher T Lyons; Erik C Wasinger; T Daniel P Stack
Journal:  J Am Chem Soc       Date:  2012-04-23       Impact factor: 15.419

3.  A colorimetric chemosensor for Cu²⁺ ion detection based on an iridium(III) complex.

Authors:  Modi Wang; Ka-Ho Leung; Sheng Lin; Daniel Shiu-Hin Chan; Daniel W J Kwong; Chung-Hang Leung; Dik-Lung Ma
Journal:  Sci Rep       Date:  2014-10-28       Impact factor: 4.379

4.  Radiative analysis of luminescence in photoreactive systems: Application to photosensitizers for solar fuel production.

Authors:  Caroline Supplis; Jérémi Dauchet; Victor Gattepaille; Fabrice Gros; Thomas Vourc'h; Jean-François Cornet
Journal:  PLoS One       Date:  2021-07-22       Impact factor: 3.240
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.