Literature DB >> 20831245

Nickel-catalyzed ring-opening three-component coupling of methylenecyclopropane with aldehydes and silanes.

Kenichi Ogata1, Yuka Atsuumi, Shin-ichi Fukuzawa.   

Abstract

A nickel-catalyzed three-component coupling between methylenecyclopropane, aldehydes, and silanes afforded silylated allylic alcohols that possess an alkyl substituent at the 2-position via cleavage of the proximal C-C bond of methylenecyclopropane.

Entities:  

Year:  2010        PMID： 20831245     DOI： 10.1021/ol101838q

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  2 in total

1.  Nickel-Catalyzed Defluorinative Coupling of Aliphatic Aldehydes with Trifluoromethyl Alkenes.

Authors:  Jichao Xiao; John Montgomery
Journal:  ACS Catal       Date:  2022-02-03       Impact factor: 13.700

2.  Copper catalyzed borocarbonylation of benzylidenecyclopropanes through selective proximal C-C bond cleavage: synthesis of γ-boryl-γ,δ-unsaturated carbonyl compounds.

Authors:  Li-Miao Yang; Hui-Hui Zeng; Xin-Lian Liu; Ai-Jun Ma; Jin-Bao Peng
Journal:  Chem Sci       Date:  2022-05-30       Impact factor: 9.969
  2 in total

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