Literature DB >> 20831186

New lithium iron pyrophosphate as 3.5 V class cathode material for lithium ion battery.

Shin-ichi Nishimura1, Megumi Nakamura, Ryuichi Natsui, Atsuo Yamada.   

Abstract

A new pyrophosphate compound Li(2)FeP(2)O(7) was synthesized by a conventional solid-state reaction, and its crystal structure was determined. Its reversible electrode operation at ca. 3.5 V vs Li was identified with the capacity of a one-electron theoretical value of 110 mAh g(-1) even for ca. 1 μm particles without any special efforts such as nanosizing or carbon coating. Li(2)FeP(2)O(7) and its derivatives should provide a new platform for related lithium battery electrode research and could be potential competitors to commercial olivine LiFePO(4), which has been recognized as the most promising positive cathode for a lithium-ion battery system for large-scale applications, such as plug-in hybrid electric vehicles.

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Year:  2010        PMID： 20831186     DOI： 10.1021/ja106297a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

1.  A 3.90 V iron-based fluorosulphate material for lithium-ion batteries crystallizing in the triplite structure.

Authors:  P Barpanda; M Ati; B C Melot; G Rousse; J-N Chotard; M-L Doublet; M T Sougrati; S A Corr; J-C Jumas; J-M Tarascon
Journal:  Nat Mater       Date:  2011-10       Impact factor: 43.841

Review 2.  Active material and interphase structures governing performance in sodium and potassium ion batteries.

Authors:  Eun Jeong Kim; P Ramesh Kumar; Zachary T Gossage; Kei Kubota; Tomooki Hosaka; Ryoichi Tatara; Shinichi Komaba
Journal:  Chem Sci       Date:  2022-05-18       Impact factor: 9.969

3.  Tailoring a fluorophosphate as a novel 4 V cathode for lithium-ion batteries.

Authors:  Young-Uk Park; Dong-Hwa Seo; Byoungkook Kim; Kun-Pyo Hong; Hyungsub Kim; Seongsu Lee; Rana A Shakoor; Keiichi Miyasaka; Jean-Marie Tarascon; Kisuk Kang
Journal:  Sci Rep       Date:  2012-10-04       Impact factor: 4.379

4.  Lithium cobalt(II) pyrophosphate, Li(1.86)CoP(2)O(7), from synchrotron X-ray powder data.

Authors:  Hui Zhou; Shailesh Upreti; Natasha A Chernova; M Stanley Whittingham
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-09-30

Review 5.  Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteries.

Authors:  Naoaki Yabuuchi; Shinichi Komaba
Journal:  Sci Technol Adv Mater       Date:  2014-07-30       Impact factor: 8.090

6.  Defects, Dopants and Lithium Mobility in Li 9 V 3 (P 2 O 7 ) 3 (PO 4 ) 2.

Authors:  Navaratnarajah Kuganathan; Sashikesh Ganeshalingam; Alexander Chroneos
Journal:  Sci Rep       Date:  2018-05-25       Impact factor: 4.379

7.  Li2SnO3 as a Cathode Material for Lithium-ion Batteries: Defects, Lithium Ion Diffusion and Dopants.

Authors:  Navaratnarajah Kuganathan; Apostolos Kordatos; Alexander Chroneos
Journal:  Sci Rep       Date:  2018-08-22       Impact factor: 4.379

8.  Defects, Diffusion, and Dopants in Li2Ti6O13: Atomistic Simulation Study.

Authors:  Navaratnarajah Kuganathan; Sashikesh Ganeshalingam; Alexander Chroneos
Journal:  Materials (Basel)       Date:  2019-09-04       Impact factor: 3.623

9.  A 3.8-V earth-abundant sodium battery electrode.

Authors:  Prabeer Barpanda; Gosuke Oyama; Shin-ichi Nishimura; Sai-Cheong Chung; Atsuo Yamada
Journal:  Nat Commun       Date:  2014-07-17       Impact factor: 14.919

10.  Lithium diffusion in Li5FeO4.

Authors:  Navaratnarajah Kuganathan; Poobalasuntharam Iyngaran; Alexander Chroneos
Journal:  Sci Rep       Date:  2018-04-11       Impact factor: 4.379
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