Literature DB >> 20830373

Group 3-centred dehydrocoupling of Me2NH·BH3.

Michael S Hill1, Gabriele Kociok-Köhn, Thomas P Robinson.   

Abstract

Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me(2)NH·BH(3) result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.

Entities:  

Year:  2010        PMID: 20830373     DOI: 10.1039/c0cc02810j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials.

Authors:  Erin M Leitao; Titel Jurca; Ian Manners
Journal:  Nat Chem       Date:  2013-10       Impact factor: 24.427

2.  Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes.

Authors:  Ross McLellan; Alan R Kennedy; Samantha A Orr; Stuart D Robertson; Robert E Mulvey
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-21       Impact factor: 15.336

3.  1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications.

Authors:  Ross McLellan; Alan R Kennedy; Robert E Mulvey; Samantha A Orr; Stuart D Robertson
Journal:  Chemistry       Date:  2017-11-03       Impact factor: 5.236

  3 in total

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