Literature DB >> 20825155

An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination.

Wenyuan Wang1, Shigeyoshi Inoue, Shenglai Yao, Matthias Driess.   

Abstract

The first isolable oxygen-bridged bis-silylene 1 has been synthesized by facile dehydrochloration of the corresponding disiloxane [LSiH(Cl)-O-SiH(Cl)L] precursor [L = PhC(NtBu)(2)] with LiN(SiMe(3))(2). Compound 1 contains three-coordinate, pyramidal Si(II) atoms in a bent disiloxane-like moiety and reacts readily with [Ni(COD)(2)] to afford the unique bis-silylene oxide nickel complex 3.

Entities:  

Year:  2010        PMID： 20825155     DOI： 10.1021/ja106458p

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  Theoretical investigation of the addition reaction of the aluminum chlorosilylenoid H(2)SiAlCl(3) with ethylene.

Authors:  Mingxia Zhang; Wenzuo Li; Zhenbo Liu; Qingzhong Li; Jianbo Cheng
Journal:  J Mol Model       Date:  2016-06-07       Impact factor: 1.810

2.  Taming a monomeric [Cu(η6-C6H6)]+ complex with silylene.

Authors:  Nasrina Parvin; Shiv Pal; Jorge Echeverría; Santiago Alvarez; Shabana Khan
Journal:  Chem Sci       Date:  2018-04-13       Impact factor: 9.825

3.  An Isolable 2,5-Disila-3,4-Diphosphapyrrole and a Conjugated Si=P-Si=P-Si=N Chain Through Degradation of White Phosphorus with a N,N-Bis(Silylenyl)Aniline.

Authors:  Yun Xiong; Shicheng Dong; Shenglai Yao; Chenshu Dai; Jun Zhu; Sebastian Kemper; Matthias Driess
Journal:  Angew Chem Int Ed Engl       Date:  2022-08-08       Impact factor: 16.823
  3 in total

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