Literature DB >> 20820504

Reactions of a β-diketiminate zinc hydride complex with heterocumulenes.

Stephan Schulz1, Tamara Eisenmann, Sarah Schmidt, Dieter Bläser, Ulrich Westphal, Roland Boese.   

Abstract

The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO(2), C(Ni-Pr)(2) and t-BuNCO at ambient temperature with insertion into the Zn-H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes.

Entities:  

Year:  2010        PMID: 20820504     DOI: 10.1039/c0cc01329c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Mononuclear Phenolate Diamine Zinc Hydride Complexes and Their Reactions With CO2.

Authors:  Neil J Brown; Jonathon E Harris; Xinning Yin; Ian Silverwood; Andrew J P White; Sergei G Kazarian; Klaus Hellgardt; Milo S P Shaffer; Charlotte K Williams
Journal:  Organometallics       Date:  2014-02-24       Impact factor: 3.876

  1 in total

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