Literature DB >> 20737081

Self-regeneration of a silylium ion catalyst in carbonyl reduction.

Kristine Müther1, Martin Oestreich.   

Abstract

The silylium ion-catalysed reduction of carbonyl compounds to the alcohol oxidation level is accomplished by exploiting the unique reactivity of a ferrocenyl-substituted silane.

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Year:  2010        PMID： 20737081     DOI： 10.1039/c0cc02139c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound.

Authors:  Allegra L Liberman-Martin; Robert G Bergman; T Don Tilley
Journal:  J Am Chem Soc       Date:  2015-04-16       Impact factor: 15.419

2.  Intramolecular Chain Hydrosilylation of Alkynylphenylsilanes Using a Silyl Cation as a Chain Carrier.

Authors:  Hidekazu Arii; Kenichi Nakabayashi; Kunio Mochida; Takayuki Kawashima
Journal:  Molecules       Date:  2016-08-01       Impact factor: 4.411

3.  Catalytic Difunctionalization of Unactivated Alkenes with Unreactive Hexamethyldisilane through Regeneration of Silylium Ions.

Authors:  Qian Wu; Avijit Roy; Elisabeth Irran; Zheng-Wang Qu; Stefan Grimme; Hendrik F T Klare; Martin Oestreich
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-23       Impact factor: 15.336

4.  Synthesis of 1-Silabenzo[d,e]isochromanes via Electrophilic Aromatic Substitution of Aldehydes Activated by Silylium Ion.

Authors:  Hidekazu Arii; Kenichi Nakao; Hideki Masuda; Takayuki Kawashima
Journal:  ACS Omega       Date:  2022-02-01

Review 5.  Recent advances in transition metal-free catalytic hydroelementation (E = B, Si, Ge, and Sn) of alkynes.

Authors:  Vitthal B Saptal; Ruibin Wang; Sehoon Park
Journal:  RSC Adv       Date:  2020-12-07       Impact factor: 4.036

6.  Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex.

Authors:  Toni T Metsänen; Daniel Gallego; Tibor Szilvási; Matthias Driess; Martin Oestreich
Journal:  Chem Sci       Date:  2015-09-14       Impact factor: 9.825
  6 in total

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