Literature DB >> 20735123

Synthesis and characterization of an iron(IV) ketimide complex.

Richard A Lewis1, Guang Wu, Trevor W Hayton.   

Abstract

Addition of 4 equiv of LiN═C(t)Bu(2) to FeCl(2) in Et(2)O/THF results in the formation of [Li(THF)](2)[Fe(N═C(t)Bu(2))(4)] (1). Oxidation of 1 with 0.5 equiv of I(2) in Et(2)O/DME yields [Li(DME)][Fe(N═C(t)Bu(2))(4)] (2) in moderate yield. Both 1 and 2 are high spin and exhibit tetrahedral geometries in the solid state. Oxidation of 1 with 1 equiv of I(2) in Et(2)O yields Fe(N═C(t)Bu(2))(4) (3) in good yield. Surprisingly, complex 3 exhibits a diamagnetic ground state and a nearly square planar geometry about the Fe center.

Entities:  

Mesh：

Substances：

Year:  2010        PMID： 20735123     DOI： 10.1021/ja104934n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Homoleptic transition metal complexes of the 7-azaindolide ligand featuring κ(1)-N1 coordination.

Authors:  Jacob A Przyojski; Monica L Kiewit; Kathlyn L Fillman; Hadi D Arman; Zachary J Tonzetich
Journal:  Inorg Chem       Date:  2015-09-17       Impact factor: 5.165

2.  Sodium Diisopropylamide: Aggregation, Solvation, and Stability.

Authors:  Russell F Algera; Yun Ma; David B Collum
Journal:  J Am Chem Soc       Date:  2017-05-30       Impact factor: 15.419

3.  Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners.

Authors:  Jason England; Erik R Farquhar; Yisong Guo; Matthew A Cranswick; Kallol Ray; Eckard Münck; Lawrence Que
Journal:  Inorg Chem       Date:  2011-03-07       Impact factor: 5.165

4.  Reversible C-C Bond Cleavage of a Cobalt Diketimide into an Elusive Cobalt Aryl Nitrenoid Complex.

Authors:  Yunjung Baek; Theodore A Betley
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-02       Impact factor: 15.336

5.  Quantifying the Electron Donor and Acceptor Abilities of the Ketimide Ligands in M(N═C(t)Bu2)4 (M = V, Nb, Ta).

Authors:  Peter L Damon; Cameron J Liss; Richard A Lewis; Simona Morochnik; David E Szpunar; Joshua Telser; Trevor W Hayton
Journal:  Inorg Chem       Date:  2015-09-30       Impact factor: 5.165

6.  The ketimide ligand is not just an inert spectator: heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex.

Authors:  Erli Lu; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

7.  Indefinitely stable iron(IV) cage complexes formed in water by air oxidation.

Authors:  Stefania Tomyn; Sergii I Shylin; Dmytro Bykov; Vadim Ksenofontov; Elzbieta Gumienna-Kontecka; Volodymyr Bon; Igor O Fritsky
Journal:  Nat Commun       Date:  2017-01-19       Impact factor: 14.919

8.  Copper(ii) ketimides in sp3 C-H amination.

Authors:  Isuri U Jayasooriya; Abolghasem Gus Bakhoda; Rachel Palmer; Kristi Ng; Nour L Khachemoune; Jeffery A Bertke; Timothy H Warren
Journal:  Chem Sci       Date:  2021-11-05       Impact factor: 9.825

9.  Synthesis of FeIII and FeIV Cyanide Complexes Using Hypervalent Iodine Reagents as Cyano-Transfer One-Electron Oxidants.

Authors:  Charafa Souilah; Sergio A V Jannuzzi; Derya Demirbas; Sergei Ivlev; Marcel Swart; Serena DeBeer; Alicia Casitas
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-29       Impact factor: 16.823
  9 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.