| Literature DB >> 20734988 |
Brian G Hashiguchi1, Kenneth J H Young, Muhammed Yousufuddin, William A Goddard, Roy A Periana.
Abstract
(IPI)Ru(II)(OH)(n)(H(2)O)(m), 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly basic solvents at higher rates than in the case of the solvent alone. Significantly, catalysis by 2 is accelerated rather than inhibited by increasing solvent basicity. The evidence is consistent with the reaction proceeding by base modulated nucleophilic CH activation.Entities:
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Year: 2010 PMID： 20734988 DOI： 10.1021/ja102518m
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419