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Literature DB >> 20731395

Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry.

Meng Zhou¹, Nathan D Schley, Robert H Crabtree.

Abstract

A series of Cp*Ir complexes can catalyze C-H oxidation, with ceric ammonium nitrate as the terminal oxidant and water as the source of oxygen. Remarkably the hydroxylation of cis-decalin and 1,4-dimethylcyclohexane proceeds with retention of stereochemistry. With H(2)O(18), cis-decalin oxidation gave (18)O incorporation into the product cis-decalol.

Entities: Chemical

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Year: 2010 PMID： 20731395 DOI： 10.1021/ja1058247

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

7 in total

1. Synthetic versatility in C-H oxidation: a rapid approach to differentiated diols and pyrans from simple olefins.

Authors: Paul E Gormisky; M Christina White
Journal: J Am Chem Soc Date: 2011-07-27 Impact factor: 15.419

2. Electron-Rich CpIr(biphenyl-2,2'-diyl) Complexes with π-Accepting Carbon Donor Ligands.

Authors: Jonathan Graeupner; Timothy P Brewster; James D Blakemore; Nathan D Schley; Julianne M Thomsen; Gary W Brudvig; Nilay Hazari; Robert H Crabtree
Journal: Organometallics Date: 2012-10-20 Impact factor: 3.876

3. Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution.

Authors: Jonathan Graeupner; Ulrich Hintermair; Daria L Huang; Julianne M Thomsen; Mike Takase; Jesús Campos; Sara M Hashmi; Menachem Elimelech; Gary W Brudvig; Robert H Crabtree
Journal: Organometallics Date: 2013-10-14 Impact factor: 3.876

4. Activated carbon for aerobic oxidation: Benign approach toward 2-benzoylbenzimidazoles and 2-benzoylbenzoxazoles synthesis.

Authors: Kai Bao; Fuqing Li; Hanjing Liu; Zhiwei Wang; Qirong Shen; Jian Wang; Weige Zhang
Journal: Sci Rep Date: 2015-06-04 Impact factor: 4.379

Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry.

1. Synthetic versatility in C-H oxidation: a rapid approach to differentiated diols and pyrans from simple olefins.

2. Electron-Rich CpIr(biphenyl-2,2'-diyl) Complexes with π-Accepting Carbon Donor Ligands.

3. Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution.

4. Activated carbon for aerobic oxidation: Benign approach toward 2-benzoylbenzimidazoles and 2-benzoylbenzoxazoles synthesis.

5. A unified photoredox-catalysis strategy for C(sp³)-H hydroxylation and amidation using hypervalent iodine.

6. Investigation of Molecular Iridium Fluorides IrF_n (n=1-6): A Combined Matrix-Isolation and Quantum-Chemical Study.

7. Molecular heterogeneous catalysts derived from bipyridine-based organosilica nanotubes for C-H bond activation.