Literature DB >> 20730137

Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation.

Monika Ali Khan1, John P Lowe, Andrew L Johnson, Alan J W Stewart, Simon E Lewis.   

Abstract

A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.

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Year:  2010        PMID: 20730137     DOI: 10.1039/c0cc01169j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  A cobalt complex of a microbial arene oxidation product.

Authors:  Dominic van der Waals; Thomas Pugh; Monika Ali Khan; Alan Jw Stewart; Andrew L Johnson; Simon E Lewis
Journal:  Chem Cent J       Date:  2011-12-07       Impact factor: 4.215

  1 in total

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