| Literature DB >> 20714539 |
Sara H Kyne1, Ching Yeh Lin, Ilhyong Ryu, Michelle L Coote, Carl H Schiesser.
Abstract
Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estimate for the rate constant for 6-endo cyclization of the 6-aza-7-ethyl-5-hexenoyl radical of (4.8 +/- 2.4) x 10(6) s(-1) at 90 degrees C in benzene, in good agreement with ONIOM-G3(MP2)-CC+COSMO-RS calculations (6.8 x 10(6) s(-1)).Entities:
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Year: 2010 PMID： 20714539 DOI： 10.1039/c0cc01262a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222