Literature DB >> 20698659

Cu(I)-catalyzed regioselective diamination of conjugated dienes via dual mechanistic pathways.

Baoguo Zhao1, Xingao Peng, Sunliang Cui, Yian Shi.   

Abstract

This paper describes the Cu(I)-catalyzed regioselective diamination of conjugated dienes using di-tert-butyldiaziridinone as nitrogen source. The internal diamination and terminal diamination likely proceed via two mechanistic pathways. Various dienes can be efficiently diaminated at the internal double bonds with high regio- and diasteroselectivity in good yield using inexpensive CuBr as catalyst.

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Year:  2010        PMID： 20698659      PMCID： PMC2933359          DOI： 10.1021/ja103838d

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  34 in total

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10.  Mechanism of N-fluorobenzenesulfonimide promoted diamination and carboamination reactions: divergent reactivity of a Pd(IV) species.

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  24 in total

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8.  Facile Cu(I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions.

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9.  Methods for direct alkene diamination, new & old.

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10.  Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins.

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