| Literature DB >> 20690728 |
Yoshimasa Makita1, Kazuya Sugimoto, Kenta Furuyoshi, Keisuke Ikeda, Shin-ichi Fujiwara, Tsutomu Shin-ike, Akiya Ogawa.
Abstract
A zinc(II)-included hemicryptophane, which has a zinc(II) center embedded in the cavity, was synthesized and characterized. The catalytic activity of the hemicryptophane was tested in the hydrolysis of methyl para-nitrophenyl carbonate (MPC). A direct comparison between the hemicryptophane and the model complex, which lacks a cavity, demonstrated that the cage structure enhanced the catalytic activity.Entities:
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Year: 2010 PMID： 20690728 DOI： 10.1021/ic100725j
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165