| Literature DB >> 20690631 |
Sudipta Raha Roy1, Asit K Chakraborti.
Abstract
Supramolecular assemblies formed by a relay of cooperative hydrogen bonds and charge-charge interactions have been identified/characterized by (+ve) ESI and MALDI-TOF-TOF MS and MS-MS studies during the aza-Michael reaction of amines with alpha,beta-unsaturated carbonyl compounds in the presence of ionic liquids (ILs) digging out the role of catalysis by ILs, forming the basis of rational design/selection as organocatalysts, and offering a diagnostic model to predict/rationalize the selectivity of the aza-Michael reaction in a competitive environment.Mesh：
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Year: 2010 PMID： 20690631 DOI： 10.1021/ol101557t
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005