Ecofriendly synthesis and solar photocatalytic activity of S-doped ZnO.

The S-doped ZnO was prepared by new ecofriendly method, which involves simple mechanochemical synthesis followed by thermal decomposition of bisthiourea zinc oxalate (BTZO) powders. The BTZO was characterized by FTIR and TG-DTA analysis while S-doped ZnO crystallite was characterized by XRD, XPS, SEM, EDXS, and photoluminescence (PL) spectra. X-ray diffraction data suggest the single phase wurtzite structure for S-doped ZnO and the incorporation of sulfur expand the lattice constants of ZnO. Room temperature PL spectra show more number of oxygen vacancies in S-doped ZnO as compare to that of pure ZnO. Photocatalytic activity of S-doped ZnO was checked by means of solar photocatalytic degradation (PCD) of resorcinol, using a batch photoreactor. The PCD efficiency of S-doped ZnO was found to be 2 times greater than that of pure ZnO. The inherent relationship between PL intensity and photocatalytic activity of S-doped ZnO was discussed.