| Literature DB >> 20684517 |
Jun Yan1, Jing Gao, De-Liang Long, Haralampos N Miras, Leroy Cronin.
Abstract
Precise control of the "one-pot" reaction conditions is employed for the assembly of a nanosized 2.8 nm cluster, [H(34)W(119)Se(8)Fe(2)O(420)](54-) (1a), which is templated using eight selenite units and two iron(III) centers. Not only is this cluster characterized structurally using X-ray crystallography, it is the largest polyoxotungstate to be observed intact in solution using ESI-MS, with a molecular mass of ca. 30,000 Da.Entities:
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Year: 2010 PMID： 20684517 DOI： 10.1021/ja104043s
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419