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Literature DB >> 20678945

Unusual ion UO(4)(-) formed upon collision induced dissociation of [UO(2)(NO(3))(3)](-), [UO(2)(ClO(4))(3)](-), [UO(2)(CH(3)COO)(3)](-) ions.

Marzena Sokalska¹, Małgorzata Prussakowska, Marcin Hoffmann, Błazej Gierczyk, Rafał Frański.

Abstract

The following ions [UO(2)(NO(3))(3)](-), [UO(2)(ClO(4))(3)](-), [UO(2)(CH(3)COO)(3)](-) were generated from respective salts (UO(2)(NO(3))(2), UO(2)(ClO(4))(3), UO(2)(CH(3)COO)(2)) by laser desorption/ionization (LDI). Collision induced dissociation of the ions has led, among others, to the formation of UO(4)(-) ion (m/z 302). The undertaken quantum mechanical calculations showed this ion is most likely to possess square planar geometry as suggested by MP2 results or strongly deformed geometry in between tetrahedral and square planar as indicated by DFT results. Interestingly, geometrical parameters and analysis of electron density suggest it is an U(VI) compound, in which oxygen atoms bear unpaired electron and negative charge.

Entities: Chemical Disease Gene

Year: 2010 PMID： 20678945 DOI： 10.1016/j.jasms.2010.06.018

Source DB: PubMed Journal: J Am Soc Mass Spectrom ISSN： 1044-0305 Impact factor: 3.109

15 in total

1. Can electrospray mass spectrometry quantitatively probe speciation? Hydrolysis of uranyl nitrate studied by gas-phase methods.

Authors: Nikos G Tsierkezos; Jana Roithová; Detlef Schröder; Milan Oncák; Petr Slavícek
Journal: Inorg Chem Date: 2009-07-06 Impact factor: 5.165

2. Ions generated from uranyl nitrate solutions by electrospray ionization (ESI) and detected with Fourier transform ion-cyclotron resonance (FT-ICR) mass spectrometry.

Authors: Sofie Pasilis; Arpád Somogyi; Kristin Herrmann; Jeanne E Pemberton
Journal: J Am Soc Mass Spectrom Date: 2006-01-18 Impact factor: 3.109

3. Reduction of pentavalent uranyl to U(IV) facilitated by oxo functionalization.

Authors: David D Schnaars; Guang Wu; Trevor W Hayton
Journal: J Am Chem Soc Date: 2009-12-09 Impact factor: 15.419

4. Expanding the crystal chemistry of actinyl peroxides: open sheets of uranyl polyhedra in Na5[(UO2)3(O2)4(OH)3](H2O)13.

Authors: Karrie-Ann Kubatko; Peter C Burns
Journal: Inorg Chem Date: 2006-08-07 Impact factor: 5.165

5. Binding of molecular O2 to di- and triligated [UO2]+.

Authors: Gary S Groenewold; Kevin C Cossel; Garold L Gresham; Anita K Gianotto; Anthony D Appelhans; John E Olson; Michael J Van Stipdonk; Winnie Chien
Journal: J Am Chem Soc Date: 2006-03-08 Impact factor: 15.419

6. Expanding the crystal chemistry of uranyl peroxides: synthesis and structures of di- and triperoxodioxouranium(VI) complexes.

Authors: Karrie-Ann Kubatko; Tori Z Forbes; Amanda L Klingensmith; Peter C Burns
Journal: Inorg Chem Date: 2007-03-27 Impact factor: 5.165

7. Electronic spectra of pure uranyl(V) complexes: characteristic absorption bands due to a U(V)O2+ core in visible and near-infrared regions.

Authors: Koichiro Mizuoka; Satoru Tsushima; Miki Hasegawa; Toshihiko Hoshi; Yasuhisa Ikeda
Journal: Inorg Chem Date: 2005-09-05 Impact factor: 5.165

8. Production and collision-induced dissociation of gas-phase, water- and alcohol-coordinated uranyl complexes containing halide or perchlorate anions.

Authors: Victor Anbalagan; Winnie Chien; Garold L Gresham; Gary S Groenewold; Michael J Van Stipdonk
Journal: Rapid Commun Mass Spectrom Date: 2004 Impact factor: 2.419