Literature DB >> 20677823

Carbonylative polymerization of propylene oxide: a multicatalytic approach to the synthesis of poly(3-hydroxybutyrate).

Erin W Dunn1, Geoffrey W Coates.   

Abstract

We report a highly efficient method for the synthesis of poly(3-hydroxybutyrate) by the carbonylative polymerization of propylene oxide. The use of compatible epoxide carbonylation and lactone polymerization catalysts allows for a one-pot reaction that eliminates the need to isolate and purify the toxic beta-butyrolactone intermediate.

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Year:  2010        PMID： 20677823     DOI： 10.1021/ja1049862

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Tandem synthesis of alternating polyesters from renewable resources.

Authors:  Carine Robert; Frédéric de Montigny; Christophe M Thomas
Journal:  Nat Commun       Date:  2011-12-13       Impact factor: 14.919

2.  A Metalated Porous Porphyrin Polymer with [Co(CO)4]- Anion as an Efficient Heterogeneous Catalyst for Ring Expanding Carbonylation.

Authors:  Jianwei Jiang; Sungho Yoon
Journal:  Sci Rep       Date:  2018-09-05       Impact factor: 4.379
  2 in total

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