Literature DB >> 20672833

Crystallographic evidence of a base-free uranium(IV) terminal oxo species.

Steven J Kraft1, Justin Walensky, Phillip E Fanwick, Michael B Hall, Suzanne C Bart.   

Abstract

The uranium(IV) terminal oxo species Tp*(2)U(O) has been synthesized by oxygen-atom transfer from pyridine-N-oxide to Tp*(2)U(2,2'-bipyridine), a trivalent uranium species with a monoanionic bipyridine ligand. Full characterization of the oxo species using (1)H NMR and IR spectroscopies, X-ray crystallography, and computational studies was performed.

Entities:  

Year:  2010        PMID： 20672833     DOI： 10.1021/ic101136j

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  6 in total

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  6 in total

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