| Literature DB >> 20669958 |
Andrew C Stevens1, Brian L Pagenkopf.
Abstract
The synthesis of siloles with substitution patterns that are continuative toward natural product synthesis are described. Their reactivity in Diels-Alder chemistry was explored through thermal, Lewis acid, and high-pressure reactions. Furthermore, bicyclic adducts were oxidatively cleaved to reveal a highly functionalized cyclohexene core.Entities:
Year: 2010 PMID： 20669958 DOI： 10.1021/ol101453e
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005