| Literature DB >> 20657946 |
Tatsuya Itou1, Yasuharu Yoshimi, Keisuke Nishikawa, Toshio Morita, Yutaka Okada, Nobuyuki Ichinose, Minoru Hatanaka.
Abstract
Deuterium exchange of a carboxy group was achieved by photochemical decarboxylation of free carboxylic acids in the presence of thiol and a small amount of D(2)O, and a deuterated product with excellent deuterium content was obtained; this reaction is a practical means of synthesizing regioselective deuterium-labelled compounds under mild reaction conditions.Entities:
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Year: 2010 PMID： 20657946 DOI： 10.1039/c0cc01464h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222