| Literature DB >> 20657938 |
Philipp Heinz1, Michael Puchberger, Maria Bendova, Stefan O Baumann, Ulrich Schubert.
Abstract
The clusters Ti(6)O(4)(OPr)(8)(OOC(CH(2))(2)C[triple bond]CH)(8) and [Zr(6)O(4)(OH)(4)(OOC(CH(2))(3)C[triple bond]CH)(12)](2) with acetylenic carboxylate ligands were prepared and structurally characterized in solution and in the crystalline state. Model reactions showed that they are suitable candidates for the formation of cluster-based inorganic-organic hybrid materials by alkyne-azide click reactions.Entities:
Year: 2010 PMID: 20657938 DOI: 10.1039/c0dt00618a
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390