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Literature DB >> 20655743

Butler-Volmer-Monod model for describing bio-anode polarization curves.

Hubertus V M Hamelers¹, Annemiek Ter Heijne, Nienke Stein, René A Rozendal, Cees J N Buisman.

Abstract

A kinetic model of the bio-anode was developed based on a simple representation of the underlying biochemical conversions as described by enzyme kinetics, and electron transfer reactions as described by the Butler-Volmer electron transfer kinetics. This Butler-Volmer-Monod model was well able to describe the measured bio-anode polarization curves. The Butler-Volmer-Monod model was compared to the Nernst-Monod model described the experimental data significantly better. The Butler-Volmer-Monod model has the Nernst-Monod model as its full electrochemically reversible limit. Contrary to the Nernst-Monod model, the Butler-Volmer-Monod model predicts zero current at equilibrium potential. Besides, the Butler-Volmer-Monod model predicts that the apparent Monod constant is dependent on anode potential, which was supported by experimental results.

Mesh：

Year: 2010 PMID： 20655743 DOI： 10.1016/j.biortech.2010.06.156

Source DB: PubMed Journal: Bioresour Technol ISSN： 0960-8524 Impact factor: 9.642

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Cited

12 in total

Butler-Volmer-Monod model for describing bio-anode polarization curves.

Review 1. Possibilities for extremophilic microorganisms in microbial electrochemical systems.

Review 2. Extracellular electron transfer mechanisms between microorganisms and minerals.

3. High Biofilm Conductivity Maintained Despite Anode Potential Changes in a Geobacter-Enriched Biofilm.

4. Processes and electron flow in a microbial electrolysis cell bioanode fed with furanic and phenolic compounds.

Review 5. Electrochemically active biofilms: facts and fiction. A review.

6. Effect of toxic components on microbial fuel cell-polarization curves and estimation of the type of toxic inhibition.

7. A Multiple Reaction Modelling Framework for Microbial Electrochemical Technologies.

Review 8. Microbial Fuels Cell-Based Biosensor for Toxicity Detection: A Review.

9. A General Model for Biofilm-Driven Microbial Electrosynthesis of Carboxylates From CO₂.

10. Low Substrate Loading Limits Methanogenesis and Leads to High Coulombic Efficiency in Bioelectrochemical Systems.

Butler-Volmer-Monod model for describing bio-anode polarization curves.

Review 1. Possibilities for extremophilic microorganisms in microbial electrochemical systems.

Review 2. Extracellular electron transfer mechanisms between microorganisms and minerals.

3. High Biofilm Conductivity Maintained Despite Anode Potential Changes in a Geobacter-Enriched Biofilm.

4. Processes and electron flow in a microbial electrolysis cell bioanode fed with furanic and phenolic compounds.

Review 5. Electrochemically active biofilms: facts and fiction. A review.

6. Effect of toxic components on microbial fuel cell-polarization curves and estimation of the type of toxic inhibition.

7. A Multiple Reaction Modelling Framework for Microbial Electrochemical Technologies.

Review 8. Microbial Fuels Cell-Based Biosensor for Toxicity Detection: A Review.

9. A General Model for Biofilm-Driven Microbial Electrosynthesis of Carboxylates From CO2.

10. Low Substrate Loading Limits Methanogenesis and Leads to High Coulombic Efficiency in Bioelectrochemical Systems.

9. A General Model for Biofilm-Driven Microbial Electrosynthesis of Carboxylates From CO₂.