Literature DB >> 20640042

Molecular Rearrangements in the Construction of Complex Molecules.

Larry E Overman1.   

Abstract

A personal account is given of the development in my laboratory of designed molecular rearrangements and their application in target-directed synthesis.

Entities:  

Year:  2009        PMID： 20640042      PMCID： PMC2902795          DOI： 10.1016/j.tet.2009.05.067

Source DB:  PubMed          Journal:  Tetrahedron        ISSN： 0040-4020            Impact factor:   2.457


  28 in total

1.  Enantioselective total synthesis of shahamin K.

Authors:  A D Lebsack; L E Overman; R J Valentekovich
Journal:  J Am Chem Soc       Date:  2001-05-23       Impact factor: 15.419

2.  The total synthesis of (+/-)-pumiliotoxin-C.

Authors:  W Oppolzer; W Fröstl
Journal:  Helv Chim Acta       Date:  1975-03-12       Impact factor: 2.164

3.  Racemization in Prins cyclization reactions.

Authors:  Ramesh Jasti; Scott D Rychnovsky
Journal:  J Am Chem Soc       Date:  2006-10-18       Impact factor: 15.419

4.  Remote oxidation of steroids by photolysis of attached benzophenone groups.

Authors:  R Breslow; S Baldwin; T Flechtner; P Kalicky; S Liu; W Washburn
Journal:  J Am Chem Soc       Date:  1973-05-16       Impact factor: 15.419

5.  An "artificial enzyme" combining a metal catalytic group and a hydrophobic binding cavity.

Authors:  R Breslow; L E Overman
Journal:  J Am Chem Soc       Date:  1970-02-25       Impact factor: 15.419

6.  A general strategy for the synthesis of cladiellin diterpenes: enantioselective total syntheses of 6-acetoxycladiell-7(16),11-dien-3-ol (deacetoxyalcyonin acetate), cladiell-11-ene-3,6,7-triol, sclerophytin A, and the initially purported structure of sclerophytin A.

Authors:  D W MacMillan; L E Overman; L D Pennington
Journal:  J Am Chem Soc       Date:  2001-09-19       Impact factor: 15.419

7.  Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity.

Authors:  Mary P Watson; Larry E Overman; Robert G Bergman
Journal:  J Am Chem Soc       Date:  2007-04-03       Impact factor: 15.419

8.  New cationic olefin cyclization-pinacol reactions. Ring-expanding cyclopentane annulations that directly install useful functionality in the cyclopentane ring.

Authors:  Larry E Overman; John P Wolfe
Journal:  J Org Chem       Date:  2002-09-06       Impact factor: 4.354

9.  Catalytic asymmetric rearrangement of allylic trichloroacetimidates. A practical method for preparing allylic amines and congeners of high enantiomeric purity.

Authors:  Carolyn E Anderson; Larry E Overman
Journal:  J Am Chem Soc       Date:  2003-10-15       Impact factor: 15.419

10.  Total synthesis of (+/-)-actinophyllic acid.

Authors:  Connor L Martin; Larry E Overman; Jason M Rohde
Journal:  J Am Chem Soc       Date:  2008-05-21       Impact factor: 15.419
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  14 in total

Review 1.  Is there no end to the total syntheses of strychnine? Lessons learned in strategy and tactics in total synthesis.

Authors:  Jeffrey S Cannon; Larry E Overman
Journal:  Angew Chem Int Ed Engl       Date:  2012-03-19       Impact factor: 15.336

2.  Development of a 2-aza-Cope-[3 + 2] dipolar cycloaddition strategy for the synthesis of quaternary proline scaffolds.

Authors:  Michael P McCormack; Tamila Shalumova; Joseph M Tanski; Stephen P Waters
Journal:  Org Lett       Date:  2010-09-03       Impact factor: 6.005

3.  Total synthesis of (+/-)- and (-)-actinophyllic acid.

Authors:  Connor L Martin; Larry E Overman; Jason M Rohde
Journal:  J Am Chem Soc       Date:  2010-04-07       Impact factor: 15.419

Review 4.  Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangements.

Authors:  Amanda C Jones; Jeremy A May; Richmond Sarpong; Brian M Stoltz
Journal:  Angew Chem Int Ed Engl       Date:  2014-03-03       Impact factor: 15.336

5.  Catalytic Alkene Difunctionalization via Imidate Radicals.

Authors:  Kohki M Nakafuku; Stacy C Fosu; David A Nagib
Journal:  J Am Chem Soc       Date:  2018-08-29       Impact factor: 15.419

6.  Directed β C-H Amination of Alcohols via Radical Relay Chaperones.

Authors:  Ethan A Wappes; Kohki M Nakafuku; David A Nagib
Journal:  J Am Chem Soc       Date:  2017-07-25       Impact factor: 15.419

7.  Origin of stereocontrol in the construction of the 12-oxatricyclo[6.3.1.0(2,7)]dodecane ring system by Prins-pinacol reactions.

Authors:  Larry E Overman; Paul S Tanis
Journal:  J Org Chem       Date:  2010-01-15       Impact factor: 4.354

8.  Asymmetric construction of rings A-D of daphnicyclidin-type alkaloids.

Authors:  Travis B Dunn; J Michael Ellis; Christiane C Kofink; James R Manning; Larry E Overman
Journal:  Org Lett       Date:  2009-12-17       Impact factor: 6.005

9.  A convergent stereoselective synthesis of quinolizidines and indolizidines: chemoselective coupling of 2-hydroxymethyl-substituted allylic silanes with imines.

Authors:  Dexi Yang; Glenn C Micalizio
Journal:  J Am Chem Soc       Date:  2009-12-09       Impact factor: 15.419

Review 10.  Natural Product Synthesis Enabled by Domino Processes Incorporating a 1,2-Rearrangement Step.

Authors:  Bastien Delayre; Qian Wang; Jieping Zhu
Journal:  ACS Cent Sci       Date:  2021-04-08       Impact factor: 14.553
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