Literature DB >> 20623070

Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation.

Laura J Sewell1, Adrian B Chaplin, Joseph A B Abdalla, Andrew S Weller.   

Abstract

[Rh(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], formed by removal of H(2) from [RhH(2)(P(t)Bu(i)Bu(2))(2)][BAr(F)(4)], is in rapid equilibrium between C-H activated Rh(III) isomers, but reacts as a masked 12-electron [Rh(P(t)Bu(i)Bu(2))(2)](+) Rh(I) cation.

Year:  2010        PMID： 20623070     DOI： 10.1039/c0dt00449a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C-H anagostic interactions and B-H agostic bonds.

Authors:  James J Race; Arron L Burnage; Timothy M Boyd; Alex Heyam; Antonio J Martínez-Martínez; Stuart A Macgregor; Andrew S Weller
Journal:  Chem Sci       Date:  2021-05-25       Impact factor: 9.825

2.  Solution, Solid-State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low-Coordinate Rhodium(III) and Iridium(III) Complexes.

Authors:  Richard C Knighton; Jack Emerson-King; Jonathan P Rourke; C André Ohlin; Adrian B Chaplin
Journal:  Chemistry       Date:  2018-02-28       Impact factor: 5.236
  2 in total

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