Literature DB >> 20623067

Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene.

Sakya S Sen1, Herbert W Roesky, Kathrin Meindl, Daniel Stern, Julian Henn, A Claudia Stückl, Dietmar Stalke.   

Abstract

Reaction of LSi-SiL (1) (L = PhC(NtBu)(2)) with diphenyl alkyne gave the first example of a room temperature stable 1,4-disilabenzene. The compound was characterized by means of single crystal X-ray diffraction studies. NICS (nucleus independent chemical shift) calculations showed that the compound has some aromatic character.

Entities:  

Year:  2010        PMID： 20623067     DOI： 10.1039/c0cc01753a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Structure and stability of propellane-like E[Formula: see text].

Authors:  Ann-Christin Andres; Julian Beckmann; Lukas Klemmer; Stephan Muth; David Scheschkewitz; Michael Springborg
Journal:  J Mol Model       Date:  2018-07-03       Impact factor: 1.810

2.  One- and Two-Electron Transfer Oxidation of 1,4-Disilabenzene with Formation of Stable Radical Cations and Dications.

Authors:  Yilin Chen; Zhikang Chen; Liuyin Jiang; Jiancheng Li; Yiling Zhao; Hongping Zhu; Herbert W Roesky
Journal:  Chemistry       Date:  2021-12-16       Impact factor: 5.020

3.  Stabilization of Reactive Nitrene by Silylenes without Using a Reducing Metal.

Authors:  Yi Ding; Samir Kumar Sarkar; Mohd Nazish; Shahila Muhammed; Daniel Lüert; Paul Niklas Ruth; Christina M Legendre; Regine Herbst-Irmer; Pattiyil Parameswaran; Dietmar Stalke; Zhi Yang; Herbert W Roesky
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-10       Impact factor: 16.823

Review 4.  Disila- and digermabenzenes.

Authors:  Takahiro Sasamori
Journal:  Chem Sci       Date:  2021-03-26       Impact factor: 9.825
  4 in total

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