Organochlorine pesticide residues in sediments from coastal environment of Cantabria (northern Spain) and evaluation of the Atlantic Ocean.

This paper documents levels of organochlorine pesticides (OCs) in coastal surface sediments from selected reference sites on the northern Atlantic Spanish coast. One hundred eight samples covering three estuaries in the Cantabrian Coast were sampled in 2006 and analyzed in the finer fraction (<63 μm) for 19 OCs by gas chromatography with electron capture detector after confirmation by mass spectrometry. Detected organochlorine pesticides were endosulfan α, endosulfan β, endosulfan sulfate, hexachlorobenzene (HCB), aldrin, dieldrin, methoxychlor, 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene (4,4'-DDE) and 1,1-dichloro-2,2-bis(4-chlorophenyl)ethane (4,4'-DDD). Total OCs concentrations ranged from 1.8 ng g(-1) dry weight (dw) to 3.9 ng g(-1) dw, showing a uniform distribution along the studied area, and being consistent with recorded levels in the literature for coastal sediments in other reference sites with low levels of pollution by OCs along the Atlantic Ocean. Endosulfan, 4,4'-DDD, HCB, aldrin, and dieldrin seemed to be ubiquitous as the legacy of past uses and deposition. OCs concentrations were significantly correlated to organic matter content and particle size distribution. No adverse biological effects derived from these pollutants are expected to take place as it can be concluded from the comparison with the existent marine sediment quality guidelines.