| Literature DB >> 20617262 |
Mariusz Molon1, Thomas Cadenbach, Timo Bollermann, Christian Gemel, Roland A Fischer.
Abstract
Two unusual compounds, [{Cp*Rh(ZnCp*)(2)(ZnMe)(ZnCl)}(2)] (1) and [Cp*(2)Rh][(Cp*Rh)(6)Zn(18)Cl(12)(mu(6)-Cl)] (2), both bearing closed shell 18-electron square pyramidal Cp*RhZn(4) building units were obtained by combined Ga/Zn, Me/Cp* and Me/Cl exchange upon treatment of [Cp*Rh(GaCp*)(2)(GaCl(2)Cp*)] with ZnMe(2) (Cp* = pentamethylcyclopentadienyl).Entities:
Year: 2010 PMID： 20617262 DOI： 10.1039/c0cc00146e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222