| Literature DB >> 20614886 |
Helen V Goulding1, Sarah E Hulse, William Clegg, Ross W Harrington, Helen Y Playford, Richard I Walton, Andrew M Fogg.
Abstract
The first anion-exchangeable framework hydroxide, Yb(3)O(OH)(6)Cl·2H(2)O, has been synthesized hydrothermally. This material has a three-dimensional cationic ytterbium oxyhydroxide framework with one-dimensional channels running through the structure in which the chloride anions and water molecules are located. The framework is thermally stable below 200 °C and can be reversibly dehydrated and rehydrated with no loss of crystallinity. Additionally, it is able to undergo anion-exchange reactions with small ions such as carbonate, oxalate, and succinate with retention of the framework structure.Entities:
Year: 2010 PMID： 20614886 DOI： 10.1021/ja104636x
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419