| Literature DB >> 20608639 |
Rajendra S Ghadwal1, Herbert W Roesky, Markus Granitzka, Dietmar Stalke.
Abstract
Reaction of IPr x SiCl(2) (1) [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene] with 1-azidoadamantane leads to functionalized N-heterocyclic carbene (NHC) 2. Silyl-substituted NHC 2 reacts easily with 1-azidoadamantane to form triazene 3, in which the exocyclic C=N bond is slightly shorter than those of regular NHC-derived triazines. 2 could serve as a promising ligand for transition metals.Entities:
Year: 2010 PMID： 20608639 DOI： 10.1021/ja104386g
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419