Literature DB >> 20589310

Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}].

Holger Braunschweig1, Peter Brenner, Paul Cogswell, Katharina Kraft, Katrin Schwab.   

Abstract

The synthesis and full characterisation of trans-[PtCl(PCy(3))(2){BiCl(2)}] is reported via the oxidative addition of the bismuth-chloride bond across [Pt(PCy(3))(2)]; this represents the first instance of such an oxidative addition reaction to be undertaken by a bismuth halide bond.

Entities:  

Year:  2010        PMID: 20589310     DOI: 10.1039/c0cc00639d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum.

Authors:  Holger Braunschweig; Mehmet Ali Celik; Rian D Dewhurst; Magdalena Heid; Florian Hupp; Sakya S Sen
Journal:  Chem Sci       Date:  2014-10-15       Impact factor: 9.825

  1 in total

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