| Literature DB >> 20589279 |
Teresa de Haro1, Cristina Nevado.
Abstract
A combination of IPrAuNTf(2) as catalyst in the presence of Selectfluor has been successfully used for the high yielding synthesis of α-fluoroenones via 1,3-acyloxy rearrangement of propargyl acetates followed by Csp(2)-F bond formation, likely involving a redox Au(I)/Au(III) catalytic cycle.Entities:
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Year: 2010 PMID： 20589279 DOI： 10.1039/c002679d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222