| Literature DB >> 20586478 |
Vlad M Iluc1, Carl A Laskowski, Carl K Brozek, Nicole D Harrold, Gregory L Hillhouse.
Abstract
Elemental sulfur reacts with a bulky bis(phosphine)nickel(0) complex to give a monomeric nickel(II) eta(2)-disulfido complex, oxidation of which results in the elimination of sulfur with dimerization to give an eta(2),eta(2)-disulfidodinickel(II) derivative in which the S-S bond can be reductively cleaved in a redox-reversible fashion.Entities:
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Year: 2010 PMID： 20586478 DOI： 10.1021/ic101242c
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165