Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Arylsilane oxidation--new routes to hydroxylated aromatics.

Literature DB >> 20582346

Arylsilane oxidation--new routes to hydroxylated aromatics.

Abstract

An efficient route to hydroxylated aromatics has been developed, via the oxidation of aryl organosilanes under functional group-tolerant and relatively mild conditions, using sub-stoichiometric amounts of fluoride promoters.

Entities: Chemical

Mesh：

Substances：

Year: 2010 PMID： 20582346 DOI： 10.1039/b924135c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

8 in total

1. Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation.

Authors: Eric M Simmons; John F Hartwig
Journal: J Am Chem Soc Date: 2010-11-15 Impact factor: 15.419

2. Iridium-Catalyzed Silylation of C-H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis.

Authors: Caleb Karmel; Zhewei Chen; John F Hartwig
Journal: J Am Chem Soc Date: 2019-04-23 Impact factor: 15.419

3. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand.

Authors: Caleb Karmel; Camille Z Rubel; Elena V Kharitonova; John F Hartwig
Journal: Angew Chem Weinheim Bergstr Ger Date: 2020-01-22

4. Suzuki-Miyaura cross-coupling of aryl carbamates and sulfamates: experimental and computational studies.

Authors: Kyle W Quasdorf; Aurora Antoft-Finch; Peng Liu; Amanda L Silberstein; Anna Komaromi; Tom Blackburn; Stephen D Ramgren; K N Houk; Victor Snieckus; Neil K Garg
Journal: J Am Chem Soc Date: 2011-04-01 Impact factor: 15.419

5. De novo Assembly of the Benzenoid Ring as a Core Strategy for Synthesis of the Isoindolinone Natural Products Isohericerin, Erinacerin A, and Sterenin A.

Authors: Chenlong Zhu; Juntian Zhang; Thomas R Hoye
Journal: Org Lett Date: 2021-09-20 Impact factor: 6.072

Arylsilane oxidation--new routes to hydroxylated aromatics.

1. Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation.

2. Iridium-Catalyzed Silylation of C-H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis.

3. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand.

4. Suzuki-Miyaura cross-coupling of aryl carbamates and sulfamates: experimental and computational studies.

5. De novo Assembly of the Benzenoid Ring as a Core Strategy for Synthesis of the Isoindolinone Natural Products Isohericerin, Erinacerin A, and Sterenin A.

6. Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds.

7. Total Synthesis of (+)-Rubriflordilactone A.

8. Total Synthesis of the Schisandraceae Nortriterpenoid Rubriflordilactone A.